diff --git a/main.pdf b/main.pdf index 44596cf..dc33372 100644 Binary files a/main.pdf and b/main.pdf differ diff --git a/main.tex b/main.tex index 55c55bf..810e116 100644 --- a/main.tex +++ b/main.tex @@ -5,9 +5,13 @@ \usepackage[T1]{fontenc} \usepackage{amsmath} \usepackage{chemfig} +\usepackage[version=4]{mhchem} \usepackage{graphicx} \usepackage{geometry} \usepackage{hyperref} +\usepackage{booktabs} +\usepackage{longtable} +\usepackage{array} % Page layout \geometry{ @@ -29,20 +33,455 @@ \subsection{Alkali metals} +\textbf{Elements:} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +3 & Li & Lithium & Lithium & 6.94 \\ +11 & Na & Sodium & Natrium & 22.99 \\ +19 & K & Potassium & Kalium & 39.10 \\ +37 & Rb & Rubidium & Rubidium & 85.47 \\ +55 & Cs & Cesium & Caesium & 132.91 \\ +87 & Fr & Francium & Francium & (223) \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{table}[h] +\centering +\small +\begin{tabular}{p{1.5cm}p{1.8cm}p{1.8cm}p{2.5cm}p{4cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ +\midrule +Li & 180.5 & 1342 & BCC & Batteries, alloys \\ +Na & 97.7 & 883 & BCC & Reducing agent, coolant \\ +K & 63.5 & 759 & BCC & Fertilizer, gun powder \\ +Rb & 39.3 & 688 & BCC & Photoelectric cells \\ +Cs & 28.4 & 671 & BCC & Atomic clocks \\ +Fr & 27 & 677 & --- & Radioactive, no use \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Preparation Methods:} + +\textit{Sodium (Na):} Electrolysis of molten NaCl: \ce{2NaCl ->[electrolysis] 2Na + Cl2 ^} + +\textit{Potassium (K):} Reduction of KCl with Na at high temperature: \ce{KCl + Na ->[high T] K ^ + NaCl} + \subsection{Alkaline earth metals} +\textbf{Elements:} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +4 & Be & Beryllium & Beryllium & 9.01 \\ +12 & Mg & Magnesium & Magnesium & 24.31 \\ +20 & Ca & Calcium & Calcium & 40.08 \\ +38 & Sr & Strontium & Strontium & 87.62 \\ +56 & Ba & Barium & Barium & 137.33 \\ +88 & Ra & Radium & Radium & (226) \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{table}[h] +\centering +\small +\begin{tabular}{p{1.5cm}p{1.8cm}p{1.8cm}p{2.5cm}p{4cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ +\midrule +Be & 1287 & 2470 & HCP & Alloys, X-ray windows \\ +Mg & 650 & 1090 & HCP & Alloys, fireworks \\ +Ca & 842 & 1484 & FCC & Reducing agent, cement \\ +Sr & 777 & 1382 & FCC & Fireworks (red) \\ +Ba & 727 & 1897 & BCC & Drilling fluids \\ +Ra & 700 & 1737 & BCC & Radioactive, obsolete \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Preparation Methods:} + +\textit{Magnesium (Mg):} Electrolysis of molten MgCl$_2$: \ce{MgCl2 ->[electrolysis] Mg + Cl2 ^} + +Alternatively, reduction of MgO with coke: \ce{MgO + C ->[high T] Mg ^ + CO ^} + +\textit{Calcium (Ca):} Electrolysis of molten CaCl$_2$ or reduction of CaO with Al + \subsection{Transition metals} +\textbf{Elements (First Row):} + +\begin{table}[h] +\centering +\small +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +21 & Sc & Scandium & Scandium & 44.96 \\ +22 & Ti & Titanium & Titanium & 47.87 \\ +23 & V & Vanadium & Vanadium & 50.94 \\ +24 & Cr & Chromium & Chromium & 52.00 \\ +25 & Mn & Manganese & Manganese & 54.94 \\ +26 & Fe & Iron & Ferrum & 55.85 \\ +27 & Co & Cobalt & Cobaltum & 58.93 \\ +28 & Ni & Nickel & Niccolum & 58.69 \\ +29 & Cu & Copper & Cuprum & 63.55 \\ +30 & Zn & Zinc & Zincum & 65.38 \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Important Elements (Other Rows):} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +47 & Ag & Silver & Argentum & 107.87 \\ +48 & Cd & Cadmium & Cadmium & 112.41 \\ +74 & W & Tungsten & Wolframium & 183.84 \\ +78 & Pt & Platinum & Platinum & 195.08 \\ +79 & Au & Gold & Aurum & 196.97 \\ +80 & Hg & Mercury & Hydrargyrum & 200.59 \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{longtable}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.2cm}p{4.5cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ +\midrule +\endfirsthead +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ +\midrule +\endhead +Ti & 1668 & 3287 & HCP & Aerospace alloys, pigments \\ +V & 1910 & 3407 & BCC & Steel alloys, catalysts \\ +Cr & 1907 & 2671 & BCC & Stainless steel, plating \\ +Mn & 1246 & 2061 & Cubic & Steel production \\ +Fe & 1538 & 2862 & BCC & Construction, machinery \\ +Co & 1495 & 2927 & HCP & Alloys, magnets \\ +Ni & 1455 & 2913 & FCC & Alloys, catalysts, coins \\ +Cu & 1085 & 2562 & FCC & Electrical wire, plumbing \\ +Zn & 419.5 & 907 & HCP & Galvanization, batteries \\ +Ag & 961.8 & 2162 & FCC & Jewelry, conductors \\ +Cd & 321.1 & 767 & HCP & Batteries, pigments \\ +W & 3422 & 5555 & BCC & Light bulb filaments \\ +Pt & 1768 & 3825 & FCC & Catalysts, jewelry \\ +Au & 1064 & 2856 & FCC & Jewelry, electronics \\ +Hg & -38.8 & 356.7 & Rhombohedral & Thermometers, lamps \\ +\bottomrule +\end{longtable} + +\textbf{Preparation Methods:} + +\textit{Iron (Fe):} Reduction in blast furnace: \ce{Fe2O3 + 3CO ->[high T] 2Fe + 3CO2} + +\textit{Copper (Cu):} Roasting sulfide ore then reduction: \ce{2Cu2S + 3O2 -> 2Cu2O + 2SO2}, then \ce{Cu2S + 2Cu2O -> 6Cu + SO2 ^} + +Alternatively, leaching and electrowinning from oxide ores. + +\textit{Zinc (Zn):} Roasting then reduction with carbon: \ce{2ZnS + 3O2 -> 2ZnO + 2SO2}, then \ce{ZnO + C -> Zn + CO} + +\textit{Chromium (Cr):} Reduction of Cr$_2$O$_3$ with aluminum (thermite process): \ce{Cr2O3 + 2Al -> 2Cr + Al2O3} + \subsection{Post-transition metals} +\textbf{Elements:} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +13 & Al & Aluminum & Aluminium & 26.98 \\ +31 & Ga & Gallium & Gallium & 69.72 \\ +49 & In & Indium & Indium & 114.82 \\ +50 & Sn & Tin & Stannum & 118.71 \\ +81 & Tl & Thallium & Thallium & 204.38 \\ +82 & Pb & Lead & Plumbum & 207.2 \\ +83 & Bi & Bismuth & Bismuthum & 208.98 \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{table}[h] +\centering +\small +\begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.2cm}p{4.5cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ +\midrule +Al & 660.3 & 2519 & FCC & Packaging, construction \\ +Ga & 29.8 & 2204 & Orthorhombic & Semiconductors, LEDs \\ +In & 156.6 & 2072 & Tetragonal & LCD screens, solders \\ +Sn & 231.9 & 2602 & Tetragonal & Solder, coatings \\ +Tl & 304 & 1473 & HCP & Rat poison (obsolete) \\ +Pb & 327.5 & 1749 & FCC & Batteries, radiation shield \\ +Bi & 271.4 & 1564 & Rhombohedral & Alloys, cosmetics \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Preparation Methods:} + +\textit{Aluminum (Al):} Hall-H\'eroult process (electrolysis of Al$_2$O$_3$ dissolved in molten cryolite): + +\ce{2Al2O3 ->[electrolysis] 4Al + 3O2 ^} + +\textit{Lead (Pb):} Roasting galena (PbS) then reduction: \ce{2PbS + 3O2 -> 2PbO + 2SO2}, then \ce{PbO + C -> Pb + CO} + +\textit{Tin (Sn):} Reduction of cassiterite (SnO$_2$) with carbon: \ce{SnO2 + 2C -> Sn + 2CO ^} + \subsection{Metalloids} +\textbf{Elements:} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +5 & B & Boron & Borium & 10.81 \\ +14 & Si & Silicon & Silicium & 28.09 \\ +32 & Ge & Germanium & Germanium & 72.64 \\ +33 & As & Arsenic & Arsenicum & 74.92 \\ +51 & Sb & Antimony & Stibium & 121.76 \\ +52 & Te & Tellurium & Tellurium & 127.60 \\ +84 & Po & Polonium & Polonium & (209) \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{table}[h] +\centering +\small +\begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.2cm}p{4.5cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ +\midrule +B & 2075 & 4000 & Rhombohedral & Glass, detergents \\ +Si & 1414 & 3265 & Diamond cubic & Semiconductors, solar cells \\ +Ge & 938.3 & 2833 & Diamond cubic & Semiconductors, optics \\ +As & 817 & 614 (subl.) & Rhombohedral & Alloys, pesticides \\ +Sb & 630.6 & 1587 & Rhombohedral & Flame retardants, alloys \\ +Te & 449.5 & 988 & Hexagonal & Alloys, solar cells \\ +Po & 254 & 962 & Cubic & Radioactive, no common use \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Preparation Methods:} + +\textit{Silicon (Si):} Reduction of silica (SiO$_2$) with carbon in electric furnace: \ce{SiO2 + 2C ->[high T] Si + 2CO ^} + +For ultrapure silicon (semiconductors): Trichlorosilane reduction: \ce{SiHCl3 + H2 ->[high T] Si + 3HCl} + \subsection{Halogen} +\textbf{Elements:} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +9 & F & Fluorine & Fluorum & 19.00 \\ +17 & Cl & Chlorine & Chlorum & 35.45 \\ +35 & Br & Bromine & Bromum & 79.90 \\ +53 & I & Iodine & Iodum & 126.90 \\ +85 & At & Astatine & Astatium & (210) \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{table}[h] +\centering +\small +\begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.5cm}p{4cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Physical State & Application/Source \\ +\midrule +F$_2$ & -219.6 & -188.1 & Pale yellow gas & Toothpaste, Teflon \\ +Cl$_2$ & -101.5 & -34.0 & Yellow-green gas & Disinfectant, PVC \\ +Br$_2$ & -7.2 & 58.8 & Red-brown liquid & Flame retardants, dyes \\ +I$_2$ & 113.7 & 184.3 & Purple-black solid & Disinfectant, photography \\ +At$_2$ & 302 & 337 & Solid (radioactive) & No practical use \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Preparation Methods:} + +\textit{Chlorine (Cl$_2$):} Electrolysis of brine (chlor-alkali process): \ce{2NaCl + 2H2O ->[electrolysis] Cl2 ^ + H2 ^ + 2NaOH} + +Laboratory: Oxidation of HCl: \ce{MnO2 + 4HCl ->[heat] MnCl2 + Cl2 ^ + 2H2O} + +\textit{Bromine (Br$_2$):} Oxidation of bromide in seawater: \ce{2Br- + Cl2 -> Br2 + 2Cl-} + +\textit{Iodine (I$_2$):} Oxidation of iodide from brine or seaweed: \ce{2I- + Cl2 -> I2 + 2Cl-} + +Or from Chile saltpeter: \ce{2NaIO3 + 5NaHSO3 -> I2 + 3NaHSO4 + 2Na2SO4 + H2O} + +\textit{Fluorine (F$_2$):} Electrolysis of KF in anhydrous HF: \ce{2HF ->[electrolysis] H2 + F2 ^} + \subsection{Noble gases} +\textbf{Elements:} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +2 & He & Helium & Helium & 4.00 \\ +10 & Ne & Neon & Neon & 20.18 \\ +18 & Ar & Argon & Argon & 39.95 \\ +36 & Kr & Krypton & Krypton & 83.80 \\ +54 & Xe & Xenon & Xenon & 131.29 \\ +86 & Rn & Radon & Radon & (222) \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{table}[h] +\centering +\small +\begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.5cm}p{4cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Physical State & Application/Source \\ +\midrule +He & -272.2 & -268.9 & Colorless gas & Balloons, cryogenics \\ +Ne & -248.6 & -246.0 & Colorless gas & Neon signs, lasers \\ +Ar & -189.3 & -185.8 & Colorless gas & Welding, light bulbs \\ +Kr & -157.4 & -153.2 & Colorless gas & Flash lamps, lasers \\ +Xe & -111.8 & -108.1 & Colorless gas & Anesthesia, ion drives \\ +Rn & -71 & -61.7 & Colorless gas & Radioactive tracer \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Preparation:} + +Noble gases are obtained by fractional distillation of liquid air (except He and Rn). + +\textit{Helium (He):} Extracted from natural gas wells. + +\textit{Radon (Rn):} Decay product of radium, collected from uranium/thorium ores. + \subsection{Other Nonmetals} +\textbf{Elements:} + +\begin{table}[h] +\centering +\begin{tabular}{ccccc} +\toprule +Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ +\midrule +1 & H & Hydrogen & Hydrogenium & 1.008 \\ +6 & C & Carbon & Carboneum & 12.01 \\ +7 & N & Nitrogen & Nitrogenium & 14.01 \\ +8 & O & Oxygen & Oxygenium & 16.00 \\ +15 & P & Phosphorus & Phosphorus & 30.97 \\ +16 & S & Sulfur & Sulfur & 32.07 \\ +34 & Se & Selenium & Selenium & 78.96 \\ +\bottomrule +\end{tabular} +\end{table} + +\textbf{Elementary Substances:} + +\begin{longtable}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.3cm}p{4.3cm}} +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Form/Structure & Application/Source \\ +\midrule +\endfirsthead +\toprule +Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Form/Structure & Application/Source \\ +\midrule +\endhead +H$_2$ & -259.2 & -252.9 & Colorless gas & Fuel, ammonia synthesis \\ +C (graphite) & 3825 & 4827 (subl.) & Hexagonal layers & Pencils, electrodes \\ +C (diamond) & 3550 & --- & Cubic crystal & Jewelry, cutting tools \\ +C (fullerene) & --- & --- & Molecular cage & Research, electronics \\ +N$_2$ & -210.0 & -195.8 & Colorless gas & Fertilizers, inert atm. \\ +O$_2$ & -218.8 & -183.0 & Colorless gas & Respiration, combustion \\ +O$_3$ (ozone) & -192.5 & -112.0 & Blue gas & Sterilization, UV shield \\ +P (white) & 44.2 & 280 & Molecular solid & Incendiaries, match \\ +P (red) & 590 & 431 (subl.) & Amorphous & Safety matches \\ +P (black) & --- & --- & Layered & Research \\ +S (rhombic) & 115.2 & 444.6 & Orthorhombic & Sulfuric acid, vulcanize \\ +S (monoclinic) & 119 & 444.6 & Monoclinic & Allotrope of sulfur \\ +Se (gray) & 221 & 685 & Hexagonal & Photocells, glass \\ +\bottomrule +\end{longtable} + +\textbf{Preparation Methods:} + +\textit{Hydrogen (H$_2$):} +\begin{itemize} +\item Steam reforming of methane: \ce{CH4 + H2O <=>[catalyst][high T] CO + 3H2} +\item Electrolysis of water: \ce{2H2O ->[electrolysis] 2H2 ^ + O2 ^} +\item Laboratory: Reaction of metals with acids: \ce{Zn + 2HCl -> ZnCl2 + H2 ^} +\end{itemize} + +\textit{Oxygen (O$_2$):} +\begin{itemize} +\item Fractional distillation of liquid air +\item Electrolysis of water: \ce{2H2O ->[electrolysis] 2H2 ^ + O2 ^} +\item Laboratory: Decomposition of KMnO$_4$: \ce{2KMnO4 ->[heat] K2MnO4 + MnO2 + O2 ^} +\item Or: \ce{2KClO3 ->[MnO2, heat] 2KCl + 3O2 ^} +\end{itemize} + +\textit{Nitrogen (N$_2$):} Fractional distillation of liquid air + +\textit{Chlorine (Cl$_2$):} See Halogen section + +\textit{Sulfur (S):} +\begin{itemize} +\item Frasch process: Melting underground sulfur with superheated water +\item Recovered from petroleum refining and natural gas processing +\end{itemize} + +\textit{Phosphorus (P):} Reduction of phosphate rock with coke and silica: + +\ce{2Ca3(PO4)2 + 6SiO2 + 10C ->[high T] 6CaSiO3 + 10CO ^ + P4 ^} + \section{Acids and bases} \section{Ions}