\documentclass[10pt,a4paper]{extarticle} % Package imports \usepackage[utf8]{inputenc} \usepackage[T1]{fontenc} \usepackage{amsmath} \usepackage{chemfig} \usepackage[version=4]{mhchem} \usepackage{graphicx} \usepackage{geometry} \usepackage{hyperref} \usepackage{booktabs} \usepackage{longtable} \usepackage{array} \usepackage{float} % Page layout \geometry{ margin=1in } % Document information \title{Chemistry Vocabulary} \author{} \date{} \begin{document} \maketitle \section*{Introduction} \section{Elements and elementary substances} \subsection{Alkali metals} \subsubsection{Elements} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 3 & Li & Lithium & Lithium & 6.94 \\ 11 & Na & Sodium & Natrium & 22.99 \\ 19 & K & Potassium & Kalium & 39.10 \\ 37 & Rb & Rubidium & Rubidium & 85.47 \\ 55 & Cs & Cesium & Caesium & 132.91 \\ 87 & Fr & Francium & Francium & (223) \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{table}[H] \centering \small \begin{tabular}{p{1.5cm}p{1.8cm}p{1.8cm}p{2.5cm}p{4cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ \midrule Li & 180.5 & 1342 & BCC & Batteries, alloys \\ Na & 97.7 & 883 & BCC & Reducing agent, coolant \\ K & 63.5 & 759 & BCC & Fertilizer, gun powder \\ Rb & 39.3 & 688 & BCC & Photoelectric cells \\ Cs & 28.4 & 671 & BCC & Atomic clocks \\ Fr & 27 & 677 & --- & Radioactive, no use \\ \bottomrule \end{tabular} \end{table} \subsubsection{Preparation Methods} \textbf{Sodium (Na):} Electrolysis of molten NaCl: \ce{2NaCl ->[electrolysis] 2Na + Cl2 ^} \textbf{Potassium (K):} Reduction of KCl with Na at high temperature: \ce{KCl + Na ->[high T] K ^ + NaCl} \subsection{Alkaline earth metals} \subsubsection{Elements} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 4 & Be & Beryllium & Beryllium & 9.01 \\ 12 & Mg & Magnesium & Magnesium & 24.31 \\ 20 & Ca & Calcium & Calcium & 40.08 \\ 38 & Sr & Strontium & Strontium & 87.62 \\ 56 & Ba & Barium & Barium & 137.33 \\ 88 & Ra & Radium & Radium & (226) \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{table}[H] \centering \small \begin{tabular}{p{1.5cm}p{1.8cm}p{1.8cm}p{2.5cm}p{4cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ \midrule Be & 1287 & 2470 & HCP & Alloys, X-ray windows \\ Mg & 650 & 1090 & HCP & Alloys, fireworks \\ Ca & 842 & 1484 & FCC & Reducing agent, cement \\ Sr & 777 & 1382 & FCC & Fireworks (red) \\ Ba & 727 & 1897 & BCC & Drilling fluids \\ Ra & 700 & 1737 & BCC & Radioactive, obsolete \\ \bottomrule \end{tabular} \end{table} \subsubsection{Preparation Methods} \textbf{Magnesium (Mg):} Electrolysis of molten MgCl$_2$: \ce{MgCl2 ->[electrolysis] Mg + Cl2 ^} Alternatively, reduction of MgO with coke: \ce{MgO + C ->[high T] Mg ^ + CO ^} \textbf{Calcium (Ca):} Electrolysis of molten CaCl$_2$ or reduction of CaO with Al \subsection{Transition metals} \subsubsection{Elements (First Row)} \begin{table}[H] \centering \small \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 21 & Sc & Scandium & Scandium & 44.96 \\ 22 & Ti & Titanium & Titanium & 47.87 \\ 23 & V & Vanadium & Vanadium & 50.94 \\ 24 & Cr & Chromium & Chromium & 52.00 \\ 25 & Mn & Manganese & Manganese & 54.94 \\ 26 & Fe & Iron & Ferrum & 55.85 \\ 27 & Co & Cobalt & Cobaltum & 58.93 \\ 28 & Ni & Nickel & Niccolum & 58.69 \\ 29 & Cu & Copper & Cuprum & 63.55 \\ 30 & Zn & Zinc & Zincum & 65.38 \\ \bottomrule \end{tabular} \end{table} \subsubsection{Important Elements (Other Rows)} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 47 & Ag & Silver & Argentum & 107.87 \\ 48 & Cd & Cadmium & Cadmium & 112.41 \\ 74 & W & Tungsten & Wolframium & 183.84 \\ 78 & Pt & Platinum & Platinum & 195.08 \\ 79 & Au & Gold & Aurum & 196.97 \\ 80 & Hg & Mercury & Hydrargyrum & 200.59 \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{longtable}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.2cm}p{4.5cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ \midrule \endfirsthead \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ \midrule \endhead Ti & 1668 & 3287 & HCP & Aerospace alloys, pigments \\ V & 1910 & 3407 & BCC & Steel alloys, catalysts \\ Cr & 1907 & 2671 & BCC & Stainless steel, plating \\ Mn & 1246 & 2061 & Cubic & Steel production \\ Fe & 1538 & 2862 & BCC & Construction, machinery \\ Co & 1495 & 2927 & HCP & Alloys, magnets \\ Ni & 1455 & 2913 & FCC & Alloys, catalysts, coins \\ Cu & 1085 & 2562 & FCC & Electrical wire, plumbing \\ Zn & 419.5 & 907 & HCP & Galvanization, batteries \\ Ag & 961.8 & 2162 & FCC & Jewelry, conductors \\ Cd & 321.1 & 767 & HCP & Batteries, pigments \\ W & 3422 & 5555 & BCC & Light bulb filaments \\ Pt & 1768 & 3825 & FCC & Catalysts, jewelry \\ Au & 1064 & 2856 & FCC & Jewelry, electronics \\ Hg & -38.8 & 356.7 & Rhombohedral & Thermometers, lamps \\ \bottomrule \end{longtable} \subsubsection{Preparation Methods} \textbf{Iron (Fe):} Reduction in blast furnace: \ce{Fe2O3 + 3CO ->[high T] 2Fe + 3CO2} \textbf{Copper (Cu):} Roasting sulfide ore then reduction: \ce{2Cu2S + 3O2 -> 2Cu2O + 2SO2}, then \ce{Cu2S + 2Cu2O -> 6Cu + SO2 ^} Alternatively, leaching and electrowinning from oxide ores. \textbf{Zinc (Zn):} Roasting then reduction with carbon: \ce{2ZnS + 3O2 -> 2ZnO + 2SO2}, then \ce{ZnO + C -> Zn + CO} \textbf{Chromium (Cr):} Reduction of Cr$_2$O$_3$ with aluminum (thermite process): \ce{Cr2O3 + 2Al -> 2Cr + Al2O3} \subsection{Post-transition metals} \subsubsection{Elements} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 13 & Al & Aluminum & Aluminium & 26.98 \\ 31 & Ga & Gallium & Gallium & 69.72 \\ 49 & In & Indium & Indium & 114.82 \\ 50 & Sn & Tin & Stannum & 118.71 \\ 81 & Tl & Thallium & Thallium & 204.38 \\ 82 & Pb & Lead & Plumbum & 207.2 \\ 83 & Bi & Bismuth & Bismuthum & 208.98 \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{table}[H] \centering \small \begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.2cm}p{4.5cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ \midrule Al & 660.3 & 2519 & FCC & Packaging, construction \\ Ga & 29.8 & 2204 & Orthorhombic & Semiconductors, LEDs \\ In & 156.6 & 2072 & Tetragonal & LCD screens, solders \\ Sn & 231.9 & 2602 & Tetragonal & Solder, coatings \\ Tl & 304 & 1473 & HCP & Rat poison (obsolete) \\ Pb & 327.5 & 1749 & FCC & Batteries, radiation shield \\ Bi & 271.4 & 1564 & Rhombohedral & Alloys, cosmetics \\ \bottomrule \end{tabular} \end{table} \subsubsection{Preparation Methods} \textbf{Aluminum (Al):} Hall-H\'eroult process (electrolysis of Al$_2$O$_3$ dissolved in molten cryolite): \ce{2Al2O3 ->[electrolysis] 4Al + 3O2 ^} \textbf{Lead (Pb):} Roasting galena (PbS) then reduction: \ce{2PbS + 3O2 -> 2PbO + 2SO2}, then \ce{PbO + C -> Pb + CO} \textbf{Tin (Sn):} Reduction of cassiterite (SnO$_2$) with carbon: \ce{SnO2 + 2C -> Sn + 2CO ^} \subsection{Metalloids} \subsubsection{Elements} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 5 & B & Boron & Borium & 10.81 \\ 14 & Si & Silicon & Silicium & 28.09 \\ 32 & Ge & Germanium & Germanium & 72.64 \\ 33 & As & Arsenic & Arsenicum & 74.92 \\ 51 & Sb & Antimony & Stibium & 121.76 \\ 52 & Te & Tellurium & Tellurium & 127.60 \\ 84 & Po & Polonium & Polonium & (209) \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{table}[H] \centering \small \begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.2cm}p{4.5cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Crystal Structure & Application/Source \\ \midrule B & 2075 & 4000 & Rhombohedral & Glass, detergents \\ Si & 1414 & 3265 & Diamond cubic & Semiconductors, solar cells \\ Ge & 938.3 & 2833 & Diamond cubic & Semiconductors, optics \\ As & 817 & 614 (subl.) & Rhombohedral & Alloys, pesticides \\ Sb & 630.6 & 1587 & Rhombohedral & Flame retardants, alloys \\ Te & 449.5 & 988 & Hexagonal & Alloys, solar cells \\ Po & 254 & 962 & Cubic & Radioactive, no common use \\ \bottomrule \end{tabular} \end{table} \subsubsection{Preparation Methods} \textbf{Silicon (Si):} Reduction of silica (SiO$_2$) with carbon in electric furnace: \ce{SiO2 + 2C ->[high T] Si + 2CO ^} For ultrapure silicon (semiconductors): Trichlorosilane reduction: \ce{SiHCl3 + H2 ->[high T] Si + 3HCl} \subsection{Halogen} \subsubsection{Elements} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 9 & F & Fluorine & Fluorum & 19.00 \\ 17 & Cl & Chlorine & Chlorum & 35.45 \\ 35 & Br & Bromine & Bromum & 79.90 \\ 53 & I & Iodine & Iodum & 126.90 \\ 85 & At & Astatine & Astatium & (210) \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{table}[H] \centering \small \begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.5cm}p{4cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Physical State & Application/Source \\ \midrule F$_2$ & -219.6 & -188.1 & Pale yellow gas & Toothpaste, Teflon \\ Cl$_2$ & -101.5 & -34.0 & Yellow-green gas & Disinfectant, PVC \\ Br$_2$ & -7.2 & 58.8 & Red-brown liquid & Flame retardants, dyes \\ I$_2$ & 113.7 & 184.3 & Purple-black solid & Disinfectant, photography \\ At$_2$ & 302 & 337 & Solid (radioactive) & No practical use \\ \bottomrule \end{tabular} \end{table} \subsubsection{Preparation Methods} \textbf{Chlorine (Cl$_2$):} Electrolysis of brine (chlor-alkali process): \ce{2NaCl + 2H2O ->[electrolysis] Cl2 ^ + H2 ^ + 2NaOH} Laboratory: Oxidation of HCl: \ce{MnO2 + 4HCl ->[heat] MnCl2 + Cl2 ^ + 2H2O} \textbf{Bromine (Br$_2$):} Oxidation of bromide in seawater: \ce{2Br- + Cl2 -> Br2 + 2Cl-} \textbf{Iodine (I$_2$):} Oxidation of iodide from brine or seaweed: \ce{2I- + Cl2 -> I2 + 2Cl-} Or from Chile saltpeter: \ce{2NaIO3 + 5NaHSO3 -> I2 + 3NaHSO4 + 2Na2SO4 + H2O} \textbf{Fluorine (F$_2$):} Electrolysis of KF in anhydrous HF: \ce{2HF ->[electrolysis] H2 + F2 ^} \subsection{Noble gases} \subsubsection{Elements} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 2 & He & Helium & Helium & 4.00 \\ 10 & Ne & Neon & Neon & 20.18 \\ 18 & Ar & Argon & Argon & 39.95 \\ 36 & Kr & Krypton & Krypton & 83.80 \\ 54 & Xe & Xenon & Xenon & 131.29 \\ 86 & Rn & Radon & Radon & (222) \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{table}[H] \centering \small \begin{tabular}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.5cm}p{4cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Physical State & Application/Source \\ \midrule He & -272.2 & -268.9 & Colorless gas & Balloons, cryogenics \\ Ne & -248.6 & -246.0 & Colorless gas & Neon signs, lasers \\ Ar & -189.3 & -185.8 & Colorless gas & Welding, light bulbs \\ Kr & -157.4 & -153.2 & Colorless gas & Flash lamps, lasers \\ Xe & -111.8 & -108.1 & Colorless gas & Anesthesia, ion drives \\ Rn & -71 & -61.7 & Colorless gas & Radioactive tracer \\ \bottomrule \end{tabular} \end{table} \subsubsection{Preparation} Noble gases are obtained by fractional distillation of liquid air (except He and Rn). \textbf{Helium (He):} Extracted from natural gas wells. \textbf{Radon (Rn):} Decay product of radium, collected from uranium/thorium ores. \subsection{Other Nonmetals} \subsubsection{Elements} \begin{table}[H] \centering \begin{tabular}{ccccc} \toprule Atomic No. & Symbol & English Name & Latin Name & Rel. Atomic Mass \\ \midrule 1 & H & Hydrogen & Hydrogenium & 1.008 \\ 6 & C & Carbon & Carboneum & 12.01 \\ 7 & N & Nitrogen & Nitrogenium & 14.01 \\ 8 & O & Oxygen & Oxygenium & 16.00 \\ 15 & P & Phosphorus & Phosphorus & 30.97 \\ 16 & S & Sulfur & Sulfur & 32.07 \\ 34 & Se & Selenium & Selenium & 78.96 \\ \bottomrule \end{tabular} \end{table} \subsubsection{Elementary Substances} \begin{longtable}{p{1.3cm}p{1.6cm}p{1.6cm}p{2.3cm}p{4.3cm}} \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Form/Structure & Application/Source \\ \midrule \endfirsthead \toprule Element & M.P. ($^\circ$C) & B.P. ($^\circ$C) & Form/Structure & Application/Source \\ \midrule \endhead H$_2$ & -259.2 & -252.9 & Colorless gas & Fuel, ammonia synthesis \\ C (graphite) & 3825 & 4827 (subl.) & Hexagonal layers & Pencils, electrodes \\ C (diamond) & 3550 & --- & Cubic crystal & Jewelry, cutting tools \\ C (fullerene) & --- & --- & Molecular cage & Research, electronics \\ N$_2$ & -210.0 & -195.8 & Colorless gas & Fertilizers, inert atm. \\ O$_2$ & -218.8 & -183.0 & Colorless gas & Respiration, combustion \\ O$_3$ (ozone) & -192.5 & -112.0 & Blue gas & Sterilization, UV shield \\ P (white) & 44.2 & 280 & Molecular solid & Incendiaries, match \\ P (red) & 590 & 431 (subl.) & Amorphous & Safety matches \\ P (black) & --- & --- & Layered & Research \\ S (rhombic) & 115.2 & 444.6 & Orthorhombic & Sulfuric acid, vulcanize \\ S (monoclinic) & 119 & 444.6 & Monoclinic & Allotrope of sulfur \\ Se (gray) & 221 & 685 & Hexagonal & Photocells, glass \\ \bottomrule \end{longtable} \subsubsection{Preparation Methods} \textbf{Hydrogen (H$_2$):} \begin{itemize} \item Steam reforming of methane: \ce{CH4 + H2O <=>[catalyst][high T] CO + 3H2} \item Electrolysis of water: \ce{2H2O ->[electrolysis] 2H2 ^ + O2 ^} \item Laboratory: Reaction of metals with acids: \ce{Zn + 2HCl -> ZnCl2 + H2 ^} \end{itemize} \textbf{Oxygen (O$_2$):} \begin{itemize} \item Fractional distillation of liquid air \item Electrolysis of water: \ce{2H2O ->[electrolysis] 2H2 ^ + O2 ^} \item Laboratory: Decomposition of KMnO$_4$: \ce{2KMnO4 ->[heat] K2MnO4 + MnO2 + O2 ^} \item Or: \ce{2KClO3 ->[MnO2, heat] 2KCl + 3O2 ^} \end{itemize} \textbf{Nitrogen (N$_2$):} Fractional distillation of liquid air \textbf{Chlorine (Cl$_2$):} See Halogen section \textbf{Sulfur (S):} \begin{itemize} \item Frasch process: Melting underground sulfur with superheated water \item Recovered from petroleum refining and natural gas processing \end{itemize} \textbf{Phosphorus (P):} Reduction of phosphate rock with coke and silica: \ce{2Ca3(PO4)2 + 6SiO2 + 10C ->[high T] 6CaSiO3 + 10CO ^ + P4 ^} \section{Acids and bases} \section{Ions} \section{Ores and alloys} \section{Reactions} \section{Hydrocarbons and their Halogen derivatives} \section{Alicyclic compounds and aromatic compounds} \section{Alcohol, phenols, ketones and aldehyde} \section{Carboxylic acids and esters} \section{Amines, amides and nitriles} \section{Thiols and thioethers} \section{Macromolecule} \section{Plastics} \section{Organic compounds in everyday life} \end{document}